IT1189279B - Procedimento per migliorare le solidita' su substrati contenenti gruppi idrossi - Google Patents
Procedimento per migliorare le solidita' su substrati contenenti gruppi idrossiInfo
- Publication number
- IT1189279B IT1189279B IT48420/82A IT4842082A IT1189279B IT 1189279 B IT1189279 B IT 1189279B IT 48420/82 A IT48420/82 A IT 48420/82A IT 4842082 A IT4842082 A IT 4842082A IT 1189279 B IT1189279 B IT 1189279B
- Authority
- IT
- Italy
- Prior art keywords
- formaldehyde
- dcda
- cyanamide
- precursor
- biguanidine
- Prior art date
Links
- 239000000758 substrate Substances 0.000 title abstract 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 12
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 abstract 4
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 abstract 4
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 abstract 3
- 239000002243 precursor Substances 0.000 abstract 3
- ZILVNHNSYBNLSZ-UHFFFAOYSA-N 2-(diaminomethylideneamino)guanidine Chemical compound NC(N)=NNC(N)=N ZILVNHNSYBNLSZ-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 abstract 2
- 238000004132 cross linking Methods 0.000 abstract 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 abstract 2
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 abstract 1
- QMNWYGTWTXOQTP-UHFFFAOYSA-N 1h-triazin-6-one Chemical compound O=C1C=CN=NN1 QMNWYGTWTXOQTP-UHFFFAOYSA-N 0.000 abstract 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 abstract 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract 1
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 abstract 1
- 150000005690 diesters Chemical class 0.000 abstract 1
- 238000009967 direct dyeing Methods 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 150000003141 primary amines Chemical class 0.000 abstract 1
- 238000004045 reactive dyeing Methods 0.000 abstract 1
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 abstract 1
- -1 urone Chemical compound 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/56—Condensation products or precondensation products prepared with aldehydes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/917—Wool or silk
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/92—Synthetic fiber dyeing
- Y10S8/924—Polyamide fiber
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
- Inorganic Insulating Materials (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3119115 | 1981-05-14 | ||
DE3119672 | 1981-05-18 | ||
DE3123664 | 1981-06-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
IT8248420A0 IT8248420A0 (it) | 1982-05-14 |
IT1189279B true IT1189279B (it) | 1988-02-04 |
Family
ID=27189325
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT48420/82A IT1189279B (it) | 1981-05-14 | 1982-05-14 | Procedimento per migliorare le solidita' su substrati contenenti gruppi idrossi |
Country Status (6)
Country | Link |
---|---|
US (1) | US4439203A (en]) |
CH (1) | CH673195B5 (en]) |
DE (1) | DE3216913C3 (en]) |
FR (1) | FR2505894B1 (en]) |
GB (1) | GB2099007B (en]) |
IT (1) | IT1189279B (en]) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4511707A (en) * | 1981-05-14 | 1985-04-16 | Sandoz Ltd. | Water-soluble precondensates useful for improving the fastness of dyes and optical brighteners on hydroxy group-containing substrates |
GB2100760B (en) * | 1981-06-22 | 1985-04-11 | Sandoz Ltd | Improvements in or relating to organic compounds |
CH669705GA3 (en]) * | 1982-08-30 | 1989-04-14 | ||
FR2540902B1 (fr) * | 1983-02-11 | 1986-05-16 | Protex Manuf Prod Chimiq | Procede de fixation des teintures realisees en colorants directs et reactifs sur fibres cellulosiques |
NL8401931A (nl) * | 1983-06-30 | 1985-01-16 | Sandoz Ag | Verbeteringen aan of met betrekking tot organische verbindingen. |
DE3329029A1 (de) * | 1983-08-11 | 1985-02-28 | Cassella Ag, 6000 Frankfurt | Verfahren zur herstellung von faerbungen mit reaktivfarbstoffen |
JPS60110987A (ja) * | 1983-11-15 | 1985-06-17 | 日東紡績株式会社 | 染色堅牢度向上法 |
DE3400052A1 (de) * | 1984-01-03 | 1985-08-14 | Sandoz-Patent-GmbH, 7850 Lörrach | Polymere verbindungen, deren herstellung und verwendung |
DE3446282A1 (de) * | 1984-01-03 | 1985-07-11 | Sandoz-Patent-GmbH, 7850 Lörrach | Faerbeverfahren |
DE3481634D1 (de) * | 1984-01-03 | 1990-04-19 | Sandoz Ag | Faerben und bedrucken von fasern. |
FR2557603B1 (fr) * | 1984-01-03 | 1988-02-19 | Sandoz Sa | Procede de teinture et de post-traitement de substrats textiles |
CH674786B5 (en]) * | 1984-01-03 | 1991-01-31 | Sandoz Ag | |
DE3446284A1 (de) * | 1984-01-03 | 1985-07-11 | Sandoz-Patent-GmbH, 7850 Lörrach | Faerbeverfahren |
FR2560240B1 (fr) * | 1984-02-24 | 1987-07-10 | Sandoz Sa | Procede de post-traitement des fibres textiles |
CH667360GA3 (en]) * | 1984-07-21 | 1988-10-14 | ||
DE3525104A1 (de) * | 1984-07-21 | 1986-01-30 | Sandoz-Patent-GmbH, 7850 Lörrach | Polykondensate, ihre herstellung und verwendung |
CH672221GA3 (en]) * | 1984-09-17 | 1989-11-15 | ||
CH669793A5 (en]) * | 1985-07-18 | 1989-04-14 | Sandoz Ag | |
GB8518489D0 (en) * | 1985-07-22 | 1985-08-29 | Sandoz Ltd | Organic compounds |
GB8526505D0 (en) * | 1985-10-28 | 1985-12-04 | Sandoz Products Ltd | Organic compounds |
GB2185499B (en) * | 1986-01-18 | 1989-11-01 | Bip Chemicals Ltd | Treatment of cellulosic textile fabrics |
US4822374A (en) * | 1986-06-17 | 1989-04-18 | Ciba-Geigy Corporation | Process for the aftertreatment of dyed cellulose fibers |
NZ221708A (en) * | 1986-09-10 | 1990-07-26 | Basf Australia | Textile printing and dyeing using hexamethoxymethyl melamine in a c 4-8 glycol and a non-cationic colourant |
DE3706176A1 (de) * | 1987-02-26 | 1988-09-08 | Sandoz Ag | Mischung mit synergistischen eigenschaften |
DE3709766A1 (de) * | 1987-03-25 | 1988-10-06 | Hoechst Ag | Verfahren zum alkali-freien faerben mit reaktivfarbstoffen |
CH678679B5 (en]) * | 1987-09-05 | 1992-04-30 | Sandoz Ag | |
GB2212175B (en) * | 1987-11-11 | 1992-01-29 | Sandoz Ltd | Aftertreatment of dyed substrates |
FR2625209B1 (fr) * | 1987-12-23 | 1990-04-27 | Charbonnages Ste Chimique | Procede de durcissement de resines aminoplastes |
GB8802794D0 (en) * | 1988-02-08 | 1988-03-09 | Sandoz Products Ltd | Improvements in/relating to organic compounds |
DE3814208A1 (de) * | 1988-04-27 | 1989-11-09 | Sandoz Ag | Verwendung von ungefaerbten und/oder gefaerbten substraten |
DE3938918A1 (de) * | 1989-11-24 | 1991-05-29 | Sandoz Ag | Mischungen mit synergistischen eigenschaften |
DE4207110A1 (de) * | 1992-03-06 | 1993-09-09 | Sandoz Ag | Polykationische polymerpraeparate und deren verwendung |
US5632781A (en) * | 1994-09-30 | 1997-05-27 | Nicca U.S.A., Inc. | Cationic polycondensate dye fixing agent and process of preparing the same |
JP3860220B2 (ja) * | 1996-11-15 | 2006-12-20 | クラリアント インターナショナル リミティド | 新規縮合生成物及びその用途 |
US6001137A (en) * | 1998-02-27 | 1999-12-14 | Encad, Inc. | Ink jet printed textiles |
EP1239025A3 (de) * | 2001-03-03 | 2003-09-03 | Clariant GmbH | Waschmittel und Wäschebehandlungsmittel enthaltend farbübertragungsinhibierend Farbfixiermittel |
EP1587854A1 (en) * | 2003-01-17 | 2005-10-26 | Clariant International Ltd. | Polymeric etheramines, their production and use |
CN100567630C (zh) * | 2003-12-29 | 2009-12-09 | 克莱里安特财务(Bvi)有限公司 | 聚合物醚胺用于改善纺织品耐氯漂牢度的用途 |
DE102018005943A1 (de) | 2018-07-19 | 2020-01-23 | ERAGON R&D GmbH | Vorrichtung und Verfahren zur Reinigung von mit Elektrolyten und Farbstoffen verunreinigtem Abwasser |
KR20240034749A (ko) * | 2021-07-09 | 2024-03-14 | 바스프 에스이 | 염색 보조제로서의 신규의 개질된 폴리알킬렌이민 |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA526517A (en) * | 1956-06-19 | Albrecht Otto | Aldehyde condensation products and process of making same | |
FR839908A (fr) * | 1937-07-03 | 1939-04-14 | Ig Farbenindustrie Ag | Procédé pour améliorer des teintures substantives |
GB576562A (en) * | 1942-06-22 | 1946-04-10 | Geigy Ag J R | Manufacture of resinous condensation products, more especially useful for the after-treatment of dyeings |
DE929642C (de) * | 1942-06-22 | 1955-06-30 | Geigy Ag J R | Verfahren zur Herstellung von wasser- bzw. saeureloeslichen, stickstoffhaltigen Kondensationsprodukten |
NL63741C (en]) * | 1944-11-17 | |||
US2595935A (en) * | 1946-08-03 | 1952-05-06 | American Cyanamid Co | Wet strength paper and process for the production thereof |
GB657753A (en) * | 1946-12-17 | 1951-09-26 | Sandoz Ltd | Process for the preparation of water-soluble organic nitrogen compounds |
GB722321A (en) * | 1950-07-27 | 1955-01-26 | Ciba Ltd | A process for improving the properties of wet fastness of dyeings or prints and compositions suitable therefor |
BE505171A (en]) * | 1954-08-09 | |||
US2902472A (en) * | 1955-03-08 | 1959-09-01 | Arkansas Company Inc | Production of dicyandiamide triethylene tetramine formaldehyde condensate |
DE1143784B (de) * | 1958-03-04 | 1963-02-21 | Ciba Geigy | Verfahren zur Verbesserung von Textilfaerbungen und -drucken |
US3141728A (en) * | 1959-12-23 | 1964-07-21 | Bayer Ag | Process for the improvement of the fastness to washing of direct dyeings on cellulose-containing materials |
GB952680A (en) * | 1961-05-10 | 1964-03-18 | Ici Ltd | New colouration process |
CH471803A (de) * | 1964-01-17 | 1969-04-30 | Ciba Geigy | Verfahren zur Herstellung von 2,4,6,8,9-Pentaaza-bizyclo-(3.3.1)-nonna-2,6-dienen |
CH451513A (de) * | 1965-03-26 | 1968-05-15 | Ciba Geigy | Verfahren zur Herstellung von neuen härtbaren stickstoffhaltigen Kondensationsprodukten |
CH456150A (de) * | 1965-03-26 | 1968-05-15 | Ciba Geigy | Verfahren zur Herstellung von neuen, härtbaren, stickstoffhaltigen Kondensationsprodukten |
US3594272A (en) * | 1969-05-05 | 1971-07-20 | Ciba Geigy Corp | Polymeric products of alkylene-polyamine-dihydrohalides,dicyandiamide,formaldehyde and epichlorohydrin and their use as retention aids in the manufacture of paper |
US3839291A (en) * | 1969-10-14 | 1974-10-01 | R Avis | Wet-strength resins and processes for making and using same |
BE786445A (fr) * | 1971-07-20 | 1973-01-19 | Ciba Geigy | Procede d'amelioration des solidites au mouille de teintures etimpressions sur des matieres fibreuses cellulosiques |
CH539732A (de) * | 1971-07-27 | 1973-01-31 | Sandoz Ag | Verfahren zur Verbesserung der Hitzebeständigkeit von Textilfärbungen |
CH472175A4 (en]) * | 1975-04-14 | 1976-10-15 | ||
GB1533434A (en) * | 1976-03-10 | 1978-11-22 | Hercules Inc | Sizing method and a sizing composition for use therein |
DE2703699A1 (de) * | 1977-01-29 | 1978-08-03 | Cassella Farbwerke Mainkur Ag | Verfahren zum faerben und bedrucken cellulosehaltiger textilmaterialien mit wasserloeslichen thioschwefelsaeurederivaten von schwefelfarbstoffen ohne zusatz von reduktionsmitteln |
DE2747358C2 (de) * | 1977-10-21 | 1986-12-04 | Bayer Ag, 5090 Leverkusen | Verfahren zur Nachbehandlung von Reaktivfärbungen |
US4240935A (en) * | 1978-12-22 | 1980-12-23 | Hercules Incorporated | Ketene dimer paper sizing compositions |
JPS55152881A (en) * | 1979-05-11 | 1980-11-28 | Nitto Boseki Co Ltd | Enhancement of dye fastness |
JPS55152879A (en) * | 1979-05-11 | 1980-11-28 | Nitto Boseki Co Ltd | Enhancement of dye fastness |
GB2070006B (en) * | 1980-02-22 | 1984-05-02 | Sandoz Ltd | Amine condencates useful in textile treatment |
-
1982
- 1982-05-04 CH CH2733/82A patent/CH673195B5/de unknown
- 1982-05-06 DE DE3216913A patent/DE3216913C3/de not_active Expired - Fee Related
- 1982-05-10 US US06/376,901 patent/US4439203A/en not_active Expired - Lifetime
- 1982-05-11 GB GB8213564A patent/GB2099007B/en not_active Expired
- 1982-05-11 FR FR8208319A patent/FR2505894B1/fr not_active Expired
- 1982-05-14 IT IT48420/82A patent/IT1189279B/it active
Also Published As
Publication number | Publication date |
---|---|
FR2505894B1 (fr) | 1986-01-10 |
DE3216913C2 (en]) | 1990-02-01 |
DE3216913A1 (de) | 1982-12-02 |
CH673195B5 (en]) | 1990-08-31 |
FR2505894A1 (fr) | 1982-11-19 |
GB2099007A (en) | 1982-12-01 |
IT8248420A0 (it) | 1982-05-14 |
GB2099007B (en) | 1985-01-09 |
CH673195GA3 (en]) | 1990-02-28 |
DE3216913C3 (de) | 1995-08-03 |
US4439203A (en) | 1984-03-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19950530 |